Coordination and structure of some transition metal piperidinium pentamethylene dithiocarbamate complexes |
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Authors: | Virendra K Sinha M N Srivastava H L Nigam |
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Institution: | (1) Chemical Laboratories, University of Allahabad, 266, Mumfordganj (Near Distillery), 211002 Allahabad, India |
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Abstract: | Summary Cobalt(II), nickel(ll), and copper(II) complexes of piperidinum pentamethylene dithiocarbamate (pipmdte) have been prepared and studied by spectral (i.r. and absorption) and magnetic methods. The M(pipmdte)CI complexes are probably four coordinate and square planar, the tridentate ligand being coordinated via the two thiocarbamate sulphur atoms and the nitrogen atom of the piperidinium group. |
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