Molecular structure of (cyanomethoxy)(dimethylamino)methane as studied by gas-phase electron diffraction and quantum-chemical calculations |
| |
| Authors: | E. P. Al’tova R. G. Kostyanovskii I. F. Shishkov |
| |
| Affiliation: | 1. Department of Chemistry, Moscow State University, Moscow, 119991, Russia
2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 117977, Russia
|
| |
| Abstract: | The molecular structure of (cyanomethoxy)(dimethylamino)methane in the gas phase is investigated by means of gas-phase electron diffraction and quantum-chemical studies for the first time. It is shown that in the gaseous state, (cyanomethoxy)(dimethylamino)methane is a mixture of gauche-anti (65%) and anti-gauche (35%) conformers. The slight influence of the anomeric effect on the compound’s structural parameters was noted. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
