Effect of Bi promoter on the performances of selective oxidation of isobutane to methacrolein over MoVO/AlPO4 catalysts |
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| Authors: | Xitao Wang Mei Li Fen Wang Shunhe Zhong Shi Jiang Sihe Wang . Tianjin |
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| Affiliation: | Key Laboratory of Applied Catalysis Science and Technology, College of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; 2. Nature Gas Company, Dagang Oil Field, Tianjin 300280, China |
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| Abstract: | The effects of Bi on the catalytic performance of selective oxidation of isobutane to methacrolein over MoVO/AlPO4 catalyst were investigated by XRD, FT-Raman, XPS, UV-vis DRS techniques. The results show that the addition of Bi component into the MoVO/AlPO4 catalyst obviously improves the catalytic performance, and the selectivity to methacrolein can increase from 14.2% to 45.1% with the increase of Bi/V molar ratio from 0 to 1. Combining the characterization results with the reaction evaluation, it is concluded that the catalytic activities of the MoV0.3Bix/AlPO4 catalysts are related to the crystalline phase composition and the dispersion of molybdenum and vanadium oxides species in general, and also to the V5+/V4+ molar ratio on the surface in particular. |
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| Keywords: | sol-gel method selective oxidation of isobutene methacrolein MoVBiO/AlPO4 catalyst |
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