Octanuclear metallocyclic Ni4Fc4 compound: synthesis, crystal structure, and electrochemical sensing for Mg2+ |
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| Authors: | Li Mingxue Cai Ping Duan Chunying Lu Feng Xie Jin Meng Qingjin |
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| Affiliation: | Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, PR China. |
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| Abstract: | New, neutral octanuclearmacrocyclic compound Ni(4)Fc(4) was achieved via self-assembly from Ni(BF(4))(2) and a ferrocene-containing bis-tridentate ligand. The compound exhibits a channeled structure with cavities inside and senses the Mg(2+) electrochemically in the solid state. |
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