Oxidative dimerization of aromatic amines using tBuOI: entry to unsymmetric aromatic azo compounds |
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Authors: | Takeda Youhei Okumura Sota Minakata Satoshi |
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Institution: | Frontier Research Base for Global Young Researchers, Graduate School of Engineering, Osaka University, Osaka 565-0871, Japan. |
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Abstract: | It's all the hype: An oxidative dimerization reaction of aromatic amines utilizing tert-butyl hypoiodite (tBuOI) under mild reaction conditions leads to aromatic azo compounds. The method allows access to unsymmetric aromatic azo compounds, which are difficult to prepare by conventional synthetic methods, in a selective manner. |
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Keywords: | arenes azo compounds dimerization iodine oxidation |
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