Photolyse von Monochloressigsäure bei 253,7 nm in wäßriger Lösung |
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| Authors: | Michael Neumann-Spallart o. Univ. Prof. Dr Nikola Getoff |
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| Affiliation: | 1. Institut für Theoretische Chemie und Strahlenchemie der Universit?t Wien, W?hringer Stra?e 38, A-1090, Wien, ?sterreich
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| Abstract: | The photolysis of 0.5 mole/l monochloroacetic acid in aqueous solution at 253.7 nm was studied and as products were determined: Cl? (?=0.34), CH2OHCOOH (?=0.19), CO2 (?=0.12), CH3COOH (?=0.08), HCHO (?=0.004) and CH4 (?=0.001). Based on these results a probable reaction mechanism is discussed to explain the rather complicated process. |
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