首页 | 本学科首页   官方微博 | 高级检索  
     检索      


The bulk properties of ethylene glycol-dimethylsulfoxide mixtures over the temperature range 278–323 K at <Emphasis Type="Italic">p</Emphasis> = 0.1 MPa
Authors:G I Egorov  D M Makarov
Institution:(1) Institute of the Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia
Abstract:The densities of ethylene glycol-dimethylsulfoxide binary mixtures were measured over the temperature range 278–323.15 K at atmospheric pressure using a vibrational densimeter. The excess molar volumes, apparent molar volumes, partial molar volumes of mixture components, volumetric thermal expansion coefficients, and partial molar volumetric thermal expansion coefficients were calculated. The excess molar volumes were described by the Redlich-Kister equation, and the partial molar volumes were calculated by two methods. The density-composition dependence contained a weak maximum, which disappeared as the temperature increased. The excess molar volumes were negative, and deviations from ideality increased as the temperature grew.
Keywords:
本文献已被 SpringerLink 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号