Structure and properties of potential nonlinear optical materials |
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Authors: | Miguel A. Mendez-Rojas Satish G. Bodige William H. Watson |
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Affiliation: | (1) Department of Chemistry, Texas Christian University, Box 298860, Fort Worth, Texas, 76129 |
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Abstract: | The synthesis, structure and properties of four ferrocene derivatives of 2-amino-1,2,3-triazole are reported. Solvatochromism is used as a screening process to assess the potential nonlinear optical behavior of these compounds. In general, this technique involves a number of assumptions, which may not be valid for organometallic complexes. Compound 3 crystallizes in space group P-1 with cell dimensions a = 5.771(2), b = 19.048(5), c = 19.343(5) Å and = 61.104(4), = 88.410(5), = 89.858(5)°; compound 5 crystallizes in space group P21/c with cell dimensions a = 12.545(2), b = 13.308(2), c = 20.513(4) Å and = 104.035(3)°; compound 9 crystallizes in space group P21/n with cell dimensions a = 12.599(4), b = 14.734(4), c = 13.619(5) Å, and = 107.63(2); compound 11 crystallizes in space group P-1 with cell dimensions a = 7.638(3), b = 9.619(4), c = 12.692(5) Å and = 77.588(7), = 78.416(7), = 71.357(7). |
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Keywords: | nonlinear optical solvatochromism 2-amino-1,2,3-triazole ferrocene potential nonlinear optical materials |
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