Complex formation between chlorine dioxide and 2,2,6,6-tetramethylpiperidin-1-oxyl |
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| Authors: | I. M. Ganiev V. V. Shereshovets I. A. Grigor'ev G. A. Tolstikov |
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| Affiliation: | (1) Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation;(2) N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent'eva, 630090 Novosibirsk, Russian Federation |
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| Abstract: | The complex formation of ClO2 with 2,2,6,6-tetramethylpiperidin-1-oxyl (TMPO) in acetone, acetonitrile,n-heptane, diethyl ether, carbon tetrachloride, and toluene was studied spectrophotometrically at −20 to +20 °C. The thermodynamic parameters of complex formation were determined at 20 °C. The transformation of the complex into the oxoammonium salt TMPO+ClO 2 − was found. Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1703–1706, October, 2000. |
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| Keywords: | chlorine dioxide 2,2,6,6-tetramethylpiperidin-1-oxyl oxoammonium salt charge transfer complex |
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