| A Facile Preparation of New Chiral Diamines/Amino-acids (Alcohols) Derived from L-Proline |
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| 作者姓名： | FU Yu-Qin
TAO Jing-Chao
DING Li-Na
LIU Wei-Min |
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| 作者单位： | FU,Yu-Qin（Department of Chemistry, Zhengzhou University, Zhengzhou 450052）
TAO,Jing-Chao（Department of Chemistry, Zhengzhou University, Zhengzhou 450052）
DING,Li-Na（Department of Chemistry, Zhengzhou University, Zhengzhou 450052）
LIU,Wei-Min（Department of Chemistry, Zhengzhou University, Zhengzhou 450052） |
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| 基金项目： | 国家自然科学基金，河南省自然科学基金 |
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| 摘 要： | Living systems use enzymes to catalyze stereoselective reactions with very high fidelity. Since proline was demonstrated as the simplest "enzyme" that mimics type Ⅰ aldolase to catalyze aldol reaction,1～3] it has attracted much attention in chemistry and other relative fields to design and synthesize highly efficient chemzyme or organocatalysts that can activate normally unreactive substances to useful asymmetric catalytic transformations.
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A Facile Preparation of New Chiral Diamines/Amino-acids (Alcohols) Derived from L-Proline |
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| FU,Yu-Qin,TAO,Jing-Chao,DING,Li-Na,LIU,Wei-Min.A Facile Preparation of New Chiral Diamines/Amino-acids (Alcohols) Derived from L-Proline[J].Chinese Journal of Organic Chemistry,2004,24(Z1):352. |
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| Authors: | FU Yu-Qin TAO Jing-Chao DING Li-Na LIU Wei-Min |
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| Abstract: | Living systems use enzymes to catalyze stereoselective reactions with very high fidelity. Since proline was demonstrated as the simplest "enzyme" that mimics type Ⅰ aldolase to catalyze aldol reaction,1～3] it has attracted much attention in chemistry and other relative fields to design and synthesize highly efficient chemzyme or organocatalysts that can activate normally unreactive substances to useful asymmetric catalytic transformations. |
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