Stereocontrolled synthesis of (RR)- and (RS)-5-hydroxy-2-methylhexanoic acid lactones : Pheromone of the carpenter bee via palladium-catalyzed reactions |
| |
| Authors: | J E Bckvall S E Bystrm JE Nystrm |
| |
| Institution: | Department of Organic Chemistry, Royal Institute of Technology, S-100 44 Stockholm Sweden |
| |
| Abstract: | (E,Z)-2,4-Hexadiene was transformed to the lactone cis-1 (  93% cis)(pheromone of the carpenter bee) in a stereospedfic reaction sequence via a Pd-calalyzed 1,4-acetoxychlorination. The same reaction sequence applied to (E,E)-2,4-hexadiene afforded the isomeric lactone trans-1 (91% trans). |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
