Ln(III) methyl and methylidene complexes stabilized by a bulky hydrotris(pyrazolyl)borate ligand |
| |
| Authors: | Zimmermann Melanie Takats Josef Kiel Gong Törnroos Karl W Anwander Reiner |
| |
| Institution: | Department of Chemistry, University of Bergen, Allégaten 41, 5007 Bergen, Norway. reiner.anwander@kj.uib.no. |
| |
| Abstract: | The reaction of Ln(AlMe(4))(3) with bulky hydrotris(pyrazolyl)borate (Tp(t)(Bu,Me))H proceeds via a sequence of methane elimination and C-H bond activation, affording unprecedented rare-earth metal ligand moieties including Ln(Me)(micro-Me)AlMe(3)] and X-ray structurally characterized "Tebbe-like" Ln(micro-CH(2))(2)AlMe(2)]. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
