New triterpenoid glycosides fromThalictrum minus L. |
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Authors: | N N Trofimova A S Gromova V I Lutsky A A Semenov S A Avilov D Li N L Owen |
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Institution: | (1) Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033 Irkutsk, Russian Federation;(2) Pacific Institute of Bioorganic Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022 Vladivostok, Russian Federation;(3) Department of Chemistry and Biochemistry, Brigham Young University, 84602 Provo, Utah, USA |
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Abstract: | From the terrestrial part ofThalictrum minus L. (Ranunculaceae) a novel triterpenoid diglycoside was isolated. The genin of this glycoside is a new cycloartane triterpenoid.
The structure of the glycoside was established on the basis of 1D and 2D NMR spectroscopy and FAB mass spectrometry as 22S,25-epoxy-3-O-β-d-galactopyranosyl-29-O-β-d-glucopyranosyl-9β, 19-cyclo-20S-lanostane-3β,16β,24S,29-tetrol.
For Part 10 see Ref. 1.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 602–605, March, 1999. |
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Keywords: | Thalictrum Ranunculaceae triterpenoid glycosides cycloartane 1D and 2D NMR spectroscopy FAB mass spectrometry |
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