Metal catalysis inside polymer frameworks: evaluation of catalyst stability and reusability |
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| Authors: | Králik Milan Kratky Vieroslav De Rosso Mirco Tonelli Massimo Lora Silvano Corain Benedetto |
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| Affiliation: | Department of Organic Technology, Slovak University of Technology, Radlinského 9, 812 37 Bratislava 1, Slovak Republic. kralik@chtf.stuba.sk |
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| Abstract: | The polymer framework of a resin-based catalyst built up with Pd nanoclusters (ca. 3 nm) dispersed inside the nanoporous domains of a thermally stable gel-type polyacrylic resin exhibits a good chemical stability under 5 bar H(2) at 40 degrees C for reasonable contact times. Chemical and physico-chemical integrity of the polymer framework are checked with a variety of instrumental analytical methods. Catalyst reusability turns out to be quite good. |
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| Keywords: | cluster compounds gel‐type resins metal catalysis palladium polymers |
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