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A comparison of thermo- and photo-chromic behaviour in films of amorphous WO3
Authors:M.R. Goulding  C.B. Thomas  R.J. Hurditch
Affiliation:1. School of Applied Physics and Physical Electronics, University of Bradford, Bradford, W. Yorks. U.K.
Abstract:Amorphous films of WO3 have been prepared by sublimation in a partiaal pressure of oxygen, and then coloured by either heat-treatment or U.V. radiation. Thermo-chromic films are extremely stable with respect to oxygen and have been compared with oxygen deficient crystals of WO3. Photo-chromic films are extremely unstable in an oxygen environment similar to hydrogen tungsten bronzes. The variation of the thermoelectric power with colouration suggests that the density-of-states in the neighbourhood of the Fermi energy differs in films coloured by the two methods.
Keywords:(present address): P.P.G. Industries   P.O. Box 31   Barbeton   Ohio   44203   U.S.A.
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