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Observation of an intermediate phase near the α-β transition of quartz by heat capacity and neutron scattering measurements
Authors:G Dolino  JP Bachheimer  CME Zeyen
Institution:Laboratoire de Spectrométrie Physique de l''Université Scientifique et Médicale de Grenoble (associé au CNRS, LA No. 8), BP 53X, 38041 Grenoble Cedex, France;Institut Laue-Langevin, BP 256X, 38042 Grenoble Cedex, France
Abstract:Recent measurements of the heat capacity of quartz have shown an anomalous behaviour near the α-β transition of quartz. This result which is well correlated with a previous thermal expansion measurement shows the existence of an intermediate phase in a temperature range of 1.3°C above the temperature of the β-α transition upon cooling. Satellite peaks have been observed by neutron diffraction, showing that this phase is modulated.
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