Electrical transport in electron beam irradiated polyacetylene

Electrical conductivity of non-doped (CH)_x decreases a little and its activation energy increases a little by the electron beam irradiation. The increase of the electrical conductivity of the irradiated (CH)_x by I₂ doping is not so remarkable compared with that of non-irradiated (CH)_x. The conductivity of heavily irradiated (CH)_x is very low even after halogen dopings.On the other hand, the effect of the electron beam irradiation on the conductivity of previously I₂ doped (CH)_x is much less compared with that doped after the electron beam irradiation. These results are explained tentatively by the role of I₂ molecules in the initial stage of radiolysis and the suppression of the cross-linking.