| 三烃基锡配合物(PhCMe_2CH_2)_3Sn[O_2C(CHRPh)] [R: OH(1), H(2)]的合成、结构、热稳定性、量子化学及毒性研究 |
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| 引用本文： | 庾江喜,冯泳兰,蒋伍玖,朱小明,张复兴,邝代治. 三烃基锡配合物(PhCMe_2CH_2)_3Sn[O_2C(CHRPh)] [R: OH(1), H(2)]的合成、结构、热稳定性、量子化学及毒性研究[J]. 无机化学学报, 2014, 30(9): 2025-2031 |
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| 作者姓名： | 庾江喜 冯泳兰 蒋伍玖 朱小明 张复兴 邝代治 |
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| 作者单位： | 功能金属有机材料湖南省普通高等学校重点实验室,衡阳师范学院化学与材料科学系,衡阳 421008 |
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| 基金项目： | 湖南省自然科学基金（No.13JJ3112），湖南省科技计划（No.2013TZ2025），湖南省高校创新平台开放基金（No.13K105），衡阳市科技计划（No.2012KJ30），衡阳师范学院协同创新中心培育项目（No.12XT02）及衡阳师范学院青年骨干教师培养计划（2012）资助项目。 |
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| 摘 要： | 甲醇中氧化双[三(2-甲基-2-苯基)丙基锡]分别与DL-扁桃酸、苯乙酸反应,合成了2个三烃基锡配合物(PhCMe2CH2)3Sn[O2CCH(OH)Ph](1)和(PhCMe2CH2)3Sn(O2CCH2Ph)(2)。经IR、1H和13C NMR、元素分析和X-射线单晶衍射表征结构。1和2均属三斜晶系,空间群P1。配合物1晶体学参数:a=0.971 1(2)nm,b=1.176 6(3)nm,c=1.700 8(4)nm,α=96.840(12)°,β=103.235(12)°,γ=110.725(11)°,Z=2,V=1.726 0(7)nm3,Dc=1.288 g·cm-3,μ(Mo Kα)=0.773 mm-1,F(000)=696,R1=0.032 5,wR2=0.087 3。配合物2晶体学参数:a=0.972 85(9)nm,b=1.161 40(11)nm,c=1.689 31(16)nm,α=96.830(5)°,β=101.935(5)°,γ=110.770(4)°,Z=2,V=1.707 1(3)nm3,Dc=1.271 g·cm-3,μ(Mo Kα)=0.778 mm-1,F(000)=680,R1=0.024 8,wR2=0.067 3。1和2的中心锡原子均为畸变四面体构型。通过分子间C-H…O或C-H…π作用,1和2分别形成一维带状或链状结构。热重分析结果表明,1和2具有良好的稳定性。毒性测试的初步结果表明,配合物1、2具有较好的环境相容性,对石螺急性毒性较小。
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| 关 键 词： | 三烃基锡配合物 扁桃酸 苯乙酸 晶体结构 毒性 |
| 收稿时间： | 2014-03-05 |
| 修稿时间： | 2014-04-08 |
Synthesis,Crystal Structure,Thermal Stability,Quantum Chemistry and Toxicity of Trialkyltin Complexes (PhCMe2CH2)3Sn[O2C(CHRPh)] [R: OH (1), H (2)] |
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| YU Jiang-Xi,FENG Yong-Lan,JIANG Wu-Jiu,ZHU Xiao-Ming,ZHANG Fu-Xing and KUANG Dai-Zhi. Synthesis,Crystal Structure,Thermal Stability,Quantum Chemistry and Toxicity of Trialkyltin Complexes (PhCMe2CH2)3Sn[O2C(CHRPh)] [R: OH (1), H (2)][J]. Chinese Journal of Inorganic Chemistry, 2014, 30(9): 2025-2031 |
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| Authors: | YU Jiang-Xi FENG Yong-Lan JIANG Wu-Jiu ZHU Xiao-Ming ZHANG Fu-Xing KUANG Dai-Zhi |
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| Affiliation: | Key Laboratory of Functional Organometallic Materials of College of Hunan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China;Key Laboratory of Functional Organometallic Materials of College of Hunan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China;Key Laboratory of Functional Organometallic Materials of College of Hunan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China;Key Laboratory of Functional Organometallic Materials of College of Hunan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China;Key Laboratory of Functional Organometallic Materials of College of Hunan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China;Key Laboratory of Functional Organometallic Materials of College of Hunan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China |
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| Abstract: | |
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| Keywords: | trialkyltin complex mandelic acid phenylacetic acid crystal structure toxicity |
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