| 锌、镉配位聚合物的合成、晶体结构及荧光性质 |
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| 引用本文： | 王庆伟,王亚男,李秀梅,刘博,孔志国.锌、镉配位聚合物的合成、晶体结构及荧光性质[J].无机化学学报,2014,30(9):2219-2224. |
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| 作者姓名： | 王庆伟 王亚男 李秀梅 刘博 孔志国 |
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| 作者单位： | 1. 环境友好材料制备与应用省部共建教育部重点实验室(吉林师范大学),四平,136000
2. 通化师范学院化学学院,通化,134002 |
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| 基金项目： | 吉林省科技发展计划（No.201205080）资助项目。 |
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| 摘 要： | 通过水热法合成了2个金属-有机配位聚合物Zn(boba)(bix)]n(1)和Cd(L1)(L2)]2n·nH2O(2)(H2boba=4,4′-(丁烷-1,2-二氧基)-二苯甲酸,bix=1,4-双(咪唑基-1-基)苯,H2L1=4-(羧基甲氧基)苯甲酸,L2=2-(4-羟基)-1H-咪唑并4,5-f]1,10]菲咯啉)。并对其进行了元素分析、红外光谱、热重和X-射线单晶衍射测定。配合物1为二维网状结构,配合物2为一维双链结构。此外,还研究了它们的荧光性质。
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| 关 键 词： | 水热合成 晶体结构 锌配合物 镉配合物 |
| 收稿时间： | 2014/3/15 0:00:00 |
| 修稿时间： | 2014/4/22 0:00:00 |
Synthesis, Crystal Structure and Fluorescent Properties of Zinc, Cadmium Coordination Polymers |
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| WANG Qing-Wei,WANG Ya-Nan,LI Xiu-Mei,LIU Bo and KONG Zhi-Guo.Synthesis, Crystal Structure and Fluorescent Properties of Zinc, Cadmium Coordination Polymers[J].Chinese Journal of Inorganic Chemistry,2014,30(9):2219-2224. |
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| Authors: | WANG Qing-Wei WANG Ya-Nan LI Xiu-Mei LIU Bo and KONG Zhi-Guo |
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| Institution: | Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Siping, Jilin 136000, China;Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Siping, Jilin 136000, China;Faculty of Chemistry, Tonghua Normal University, Tonghua, Jilin 134002, China;Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Siping, Jilin 136000, China;Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Siping, Jilin 136000, China |
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| Abstract: | Two metal-organic coordination polymers Zn(boba)(bix)]n (1) and Cd(L1)(L2)]2n·nH2O (2) (H2boba=4,4'-(butane-1,4-diyldioxy)dibenzoic acid, bix=1,4-bis(imidazol-1-yl)-benzene, H2L1=4-(carboxy-methoxy)-benzoic acid, L2=2-(4-hydroxyl)-1H-imidazo4,5-f]1,10]phenanthroline) have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. Complex 1 is 2D network structure, complex 2 exhibits 1D double chain structure. Moreover, their luminescent properties have been investigated in the solid state. CCDC: 987090, 1; 988451, 2. |
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| Keywords: | hydrothermal synthesis crystal structure zinc complex cadmium complex fluorescence |
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