Thermal Stability and Non-isothermal Decomposition Kinetics. Heteropolynuclear compounds of Cu(II) |
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Authors: | M. Badea R. Olar E. Cristurean D. Marinescu M. Brezeanu C. Calina-Soradi E. Segal |
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Affiliation: | (1) Department of Inorganic Chemistry, Bucharest University, 23 Dumbrava Rosie St., Bucharest, Romania;(2) Anticorrosive Protection Paints and Varnishes Research Institute, 7 Gral Magheru Blvd., S.I Bucharest, Romania;(3) Department of Physical Chemistry, University of Bucharest, Bulevardul Elisabeta 4-12, Bucharest, Romania |
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Abstract: | Data concerning the thermal behaviour of four heteropolynuclear compounds with the general formula [CuML(CH3COO)3] whereM=Ni(II), Zn(II), Mn(II) and Co(II); LH=2-amino-5-mercapto-1,2,3-thiadiazole were obtained. For the kinetically workable decomposition steps the values of the kinetic parameters were estimated. This revised version was published online in July 2006 with corrections to the Cover Date. |
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Keywords: | coordination compounds non-isothermal kinetics thermal stability |
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