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The Thermoviscoelastic Constitutive Equation of PP and PA Blends and Its Rate Temperature Equivalency at High Strain Rates
Authors:Shi Shaoqiu  Yu Bing  Wang Lili
Affiliation:Faculty of Engineering, Ningbo University, 315211, P.R.China
Abstract:By using Instron 1342 testing system and an improved SHPB technique, PP/PA blends are tested at a wide range of strain rates from 10−4 up to 103 s−1 and at a temperature range of 25–80 °C. Their mechanical responses are shown to be sensitive both to the strain rate and temperature. Based on the experimental data of 113 blends at a wide range of strain rates from 10−4 up to 103 s−1 and at a temperature range of 25–80 °C, it is shown that the mechanical behavior of this PP/PA blends can be described with ZWT thermoviscoelastic constitutive equation. The corresponding thermoviscoelastic parameters for 113 blends are obtained. The predicted theoretical results coincide quite well with the experimental data.The experimental results also reveal that the rate/time-temperature equivalence relation is shown for PP/PA blends. Raising the temperature is equivalent to the increasing of time (the decreasing of strain rate). Conversely, decreasing the temperature is equivalent to the decreasing of time (the increasing of strain rate). Through introducing a dimensionless parameter equation image , two characteristic parameters: strain rate equation image and temperature T are put together to this unified parameter Z. From experimental results, A/k is fitted, A/k = 8.595 °C, and a unified curve characterizing the rate/time –temperature equivalence relation is obtained.
Keywords:polymer blends  rate/time-temperature equivalence  thermoviscoelastic response
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