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Evaluation of the Physical-Chemical Properties of Poly(ethylene oxide)-block-Poly(propylene oxide) by Different Characterization Techniques
Authors:Claudia Mansur  Luciana Spinelli  Gaspar González  Elizabete F Lucas
Institution:1. Macromolecules Institute Professora Eloisa Mano, Federal University of Rio de Janeiro (IMA/UFRJ), PO Box: 68525, 21945-970, Rio de Janeiro, RJ, Brazil;2. Petrobras Research Center (CENPES), Ilha do Fundão, Q. 7, Cidade Universitária, 21949-900, Rio de Janeiro, RJ, Brazil
Abstract:Summary: A surfactant's efficiency for a given application is dependent on its chemical structure and physical-chemical properties in solution, including surfactant solubility as a function of concentration and temperature as well as adsorption and aggregation behavior. This review work describes the main physical-chemical properties ascertained by means of various characterization techniques, which can be used to study nonionic surfactants based on poly(ethylene oxide)-block-poly(propylene oxide) (PEO-PPO). Among these, some are widely used and others are relatively new for this type of application.
Keywords:block copolymers  phase diagrams  surfactants  surfaces
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