New path for the decomposition of bipolar adducts formed by the reaction of olefin oxides with diphenyl-β-hydroxyalkylphosphines |
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| Authors: | A D Malievskii O I Gorbunova N A Bondarenko E N Tsvetkov |
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| Institution: | (1) Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow;(2) Institute for Physiologically Active Materials, Academy of Sciences of the USSR, Chernogolovka |
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| Abstract: | Conclusions A new decomposition path to olefin oxide and phosphine has been found for the R3P+C-CO-bipolar ion that forms in the olefin oxide-diphenyl- -hydroxyalkylphosphine system. It takes place along with the known degradation paths (formation of unsaturated and carbonyl compounds).Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimcheskaya, No. 1, pp. 169–173, January, 1985. |
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