Reactivity of acrylic monomers |
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| Authors: | E. Dumitriu Sp. Oprea S. Maxim A. Nathanson M. Dima |
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| Affiliation: | (1) Department of Organic Chemistry Faculty of Chemical Technology, Bahlui Stînga Street 7, Jassy, Rumania |
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| Abstract: | Summary The copolymerization of N,N-diethylacrylamide (Ml) with methyl acrylate (M2) was investigated and reactivity ratiosr1= 0.41 andr2 = 0.52 obtained. Also the distribution of diad fractions was calculated and the results were interpreted in terms of the product of reactivity ratios. The tendency of the two monomers to alternate was explained on the basis of differences in polatities between the double bonds, this explanation being supported both by the values ofe parameter and NMR spectroscopy data. A copolymerization mechanism was suggested.With 5 figures and 2 tables |
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