New Cu(II) compounds with ligands synthesized through nucleophilic addition of pyrazoles to dicyanamide. Synthesis,crystal structures and spectroscopy |
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| Authors: | Gerard A. van Albada Maarten G. van der Horst Stefan M. Bijvoets Ilpo Mutikainen Urho Turpeinen Jan Reedijk |
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| Affiliation: | 1. Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands;2. Laboratory of Inorganic Chemistry, Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), 00014 Helsinki, Finland |
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| Abstract: | Three newly synthesized ligands, i.e. (pyrazolecarbimido)-cyanoamine (abbreviated as Hdcapz), (3-methylpyrazolecarbimido)cyanoamine (abbreviated as Hdcampz) and (3,5-dimethylpyrazolecarbimido)cyanoamine (abbreviated as Hdcadmpz) are presented in this study, including the X-ray crystal structures for two of them, as well as their coordination behaviour with respect to Cu(II). |
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| Keywords: | Crystal structure Copper Dicyanamide Trinuclear |
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