Equilibrium and kinetic studies of reactions of [MnN(H2O)(CN)4] with monodentate ligands and the molecular structure of [MnN(NCS)(CN)4] |
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| Authors: | Hendrik J. van der Westhuizen Andreas Roodt Reinout Meijboom |
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| Affiliation: | 1. Department of Chemistry, University of Johannesburg, P.O. Box 524, Auckland Park 2006, South Africa;2. Department of Chemistry, University of the Free State, P.O. Box 339, Bloemfontein 9300, South Africa |
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| Abstract: | The dissolution of [(CH3)N]2Na[MnN(CN)5]·H2O in water results in the dissociation of the labile trans-CN ligand to form [MnN(H2O)(CN)4]2−(aq). The formed aqua complex reacts rapidly with a number of nucleophiles such as NCS− and N3−. Here we report the single crystal X-ray structure of the reaction products of as well as the equilibrium and kinetic behaviour of [MnN(H2O)(CN)4]2− in solution. |
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| Keywords: | Manganese Nitrido complex X-ray structure Kinetics |
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