Preparation and compounds of (8-methoxynaphth-1-yl)diphenylphosphine |
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Authors: | Fergus R Knight Amy L FullerAlexandra MZ Slawin J Derek Woollins |
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Institution: | School of Chemistry, University of St. Andrews, St. Andrews, Fife KY16 9ST, UK |
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Abstract: | Reaction of 8-methoxy-1-naphthyllithium (2) with one equivalent of chlorodiphenylphosphine gives the novel (8-methoxynaphth-1-yl)diphenylphosphine (3) which was oxidised to the corresponding sulfide (4) and selenide (5) by reaction with sulfur and selenium, respectively. The P?O peri distance is significantly increased in 4 and 5 at 2.819(3) 2.793(3)] and 2.827(3) 2.806(3)] ? values in square brackets are for the second independent molecules in each case] relative to the value in 3 of 2.678(2) Å. There are short E?O interactions ie O(1)?S(1) 3.165(3) 3.124(3)], O(1)?Se(1) 3.247(3) 3.200(2)] ? and these may be repulsive and responsible for the increased P?O separation. The use of the naphthalene backbone in the synthesis of a potential hemilabile ligand is demonstrated by the synthesis and X-ray structure of (8-methoxynaphth-1-yl)diethoxyphosphine ruthenium p-cymene dichloride (6). |
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Keywords: | Ligand Phosphorus X-ray structure Peri substitution |
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