Synthesis and characterization of new air stable primary amido substituted diborane(4) derivatives |
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Authors: | Erkan Fırıncı,H. Can Sö yleyici,Emrah Giziroğlu,Ersin Temel,Orhan Bü yü kgü ngö r,Yü ksel Şahin |
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Affiliation: | 1. Adnan Menderes University, Department of Chemistry, 09010 Ayd?n, Turkey;2. Ondokuz May?s University, Department of Physics, 55139 Samsun, Turkey |
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Abstract: | Three new diborane(4) derivatives, 1,2-bis(2,4,6-trimethylanilide)-1,2-bis(dimethyamido)diborane(4) (1), 1,2-bis(2,4,6-trimethylanilide)-1,2-bis(duryl)diborane(4) (2) and 1,2-bis(anilide)-1,2-bis(duryl)diborane(4) (3), have been synthesized and characterized by means of elemental analysis, IR, 1H, 13C and 11B NMR spectroscopy. Additionally, the structures of compounds 1 and 2 have been determined by the single crystal X-ray diffraction technique. The compounds 1 and 2 crystallize in the monoclinic P21/c space group. All of the compounds were found to be air stable. |
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Keywords: | Boranes Diborane(4) Air stable X-ray structures |
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