Synthesis,electrochemical, in situ spectroelectrochemical and in situ electrocolorimetric characterization of new metal-free and metallophthalocyanines substituted with 4-{2-[2-(1-naphthyloxy)ethoxy]ethoxy} groups |
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Authors: | Irfan Acar Zekeriya B?y?kl?o?lu At?f Koca Halit Kantekin |
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Institution: | 1. Department of Chemistry, Faculty of Arts & Sciences, Karadeniz Technical University, 61080 Trabzon, Turkey;2. Macka Vocational School, Karadeniz Technical University, 61750 Macka, Trabzon, Turkey;3. Department of Chemical Engineering, Faculty of Engineering, Marmara University, Göztepe 34722, ?stanbul, Turkey |
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Abstract: | The synthesis of novel metal-free and metallophthalocyanines Ni(II), Zn(II), Co(II), Cu(II)] were prepared by cyclotetramerization of a novel 4-{2-2-(1-naphthyloxy)ethoxy]ethoxy}phthalonitrile and the corresponding metal salts (NiCl2, Zn(CH3COO)2, CoCl2 and CuCl2). The structures of the target compounds were confirmed using elemental analysis, IR, 1H NMR, 13C NMR, UV–Vis and MS spectral data. Voltammetric and in situ spectroelectrochemical measurements show that while cobalt phthalocyanine complex gives both metal-based and ring-based redox processes, metal-free, and zinc phthalocyanines show only ring-based reduction and oxidation processes. All complexes decomposed and coated on the electrode as nonconductive film at positive potential window of the electrolyte. An in situ electrocolorimetric method has been applied to investigate color of the electro-generated anionic and cationic forms of the complexes. |
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Keywords: | Phthalocyanine Phthalonitrile Cyclic voltammetry Synthesis Spectroelectrochemistry Chromaticity diagram |
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