Investigation of the structure and energetics ofΒ-diketonates. VII. Molecular structure of Ga(DPM)3 according to gas phase electron diffraction data |
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| Authors: | N V Belova G V Girichev N I Giricheva N P Kuzmina |
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| Institution: | (1) Ivanovo State Chemical Engineering Academy, Ivanovo State University, Russia;(2) M. V. Lomonosov Moscow State University, Russia |
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| Abstract: | A combined electron diffraction and mass spectrometric study of the saturated vapor over gallium tris-dipivaloylmethanate
was performed. It was found that the vapor contains only the monomeric molecules Ga(DPM)3
of C3 symmetry, for which the ra, rg,and ra parameters were determined. The force constant f(Ga-O) was estimated from the experimental value of the vibration amplitude
1(Ga-O). 1999. |
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