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Phosphate ore beneficiation via determination of phosphorus-to-silica ratios by Laser Induced Breakdown Spectroscopy
Authors:George Asimellis   Aggelos Giannoudakos  Michael Kompitsas
Affiliation:

aFaculty of Physics, Aristotle University of Thessaloniki, Thessaloniki 54124, Greece

bSchool of Chemical Engineering, National Technical University of Athens, 9, Iroon, Polytechniou Str., Zografou, 15780 Athens, Greece

cNational Hellenic Research Foundation, Theoretical and Physical Chemistry Institute, 48, Vasileos Konstantinou Ave., 11635 Athens, Greece

Abstract:We report development and application of an in-situ applicable method to determine phosphate ore rock quality based on Laser-Induced Breakdown Spectroscopy (LIBS). This is an economically viable method for real-time evaluation of ore phosphate rocks in order to separate high-silica pebbles prior to deep beneficiation. This is achieved by monitoring relative emission line intensities from key probe elements via single laser ablation shots: the ratio of the phosphorous to silica line intensities (P/Si ratio) provides a simple and reliable indicator of ore rock quality. This is a unique LIBS application where no other current analytical spectroscopic method (ICP or XRF) can be applied. Method development is discussed, and results with actual ore samples are presented.
Keywords:Laser-induced breakdown spectroscopy   Phosphorus detection   Phosphate mine beneficiation
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