Trifluoromethylation of carbonyl compounds with sodium trifluoroacetate |
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| Authors: | Ying Chang Chun Cai |
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| Affiliation: | aSchool of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiaoling Wei, Nanjing 210094, China |
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| Abstract: | In the presence of copper(I) iodide as catalyst, a variety of carbonyl compounds, such as aldehydes, ketones and acid anhydrous, could be trifluoromethylated with sodium trifluoroacetate to give the corresponding alcohols in moderate to high yields, and a possible mechanism was proposed to explain the roles of catalyst and solvent in the reaction system. |
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| Keywords: | Trifluoromethylation Sodium trifluoroacetate Carbonyl compounds Mechanism |
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