Stereoselective synthesis of insect sex pheromone analogs having a fluorine atom on their double bonds |
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| Authors: | Tong Guan |
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| Institution: | Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan |
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| Abstract: | Insect sex pheromone analogs having a fluorine atom on their double bonds, (9E,11E)-1-acetoxy-9-fluorotetradecadiene, (10E,12E)-13-fluorohexadecadien-1-ol, (9Z,11E)-1-acetoxy-9-fluorotetradecadiene, (10E,12Z)-13-fluorohexadecadien-1-ol were stereoselectively synthesized using cross-coupling reactions of alkenylboranes with (E)- or (Z)-2-fluoro-1-iodo-1-alkenes, stereoselectively prepared from 1-alkynes by our currently developed methods. |
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| Keywords: | Pheromone analogs Fluorine Conjugated diene Cross-coupling reaction |
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