| Synthesis and Crystal Structure of the Copper Complex of 7，16-Bis（2-hyd roxy-5-met hylbenzyl）-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane |
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| 引用本文： | 马淑兰 朱文祥 郭倩玲 刘迎春 许妙琼. Synthesis and Crystal Structure of the Copper Complex of 7，16-Bis（2-hyd roxy-5-met hylbenzyl）-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane[J]. 中国化学, 2004, 22(1): 60-63. DOI: 10.1002/cjoc.20040220114 |
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| 作者姓名： | 马淑兰 朱文祥 郭倩玲 刘迎春 许妙琼 |
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| 作者单位： | DepartmentofChemistry,BeijingNormalUniversity,Beijing100875,China |
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| 基金项目： | the Municipal Natural Science Foundation of Beijing (No. 2022011). |
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| 摘 要： | A lariat crown ether ligand 7,16-bis (2-hydroxy-5-methylbenzyl)- 1,4,10,13-tetraoxa-7,16-diazacyclooctadeeane (L1) has been prepared via one-pot Mannich reaction. Its copper(Ⅱ) complex Cu-L1 was synthesized and characterized by elemental analysis, IR and UV-visible spectroscopy. The crystal structure of the complex has been determined by X-ray diffraction analysis. The result shows that the copper(Ⅱ) ion is six-coordinated by two nitrogen and four oxygen atoms, two from the crown ether and the other two from the deprotonated phenolate anions, forming an elongated octahedral complex. Electrochemical study indicates that the complex undergoes reversible reduction in DMF solution.
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| 关 键 词： | 合成 晶体结构 铜化合物 有机化合物 循环伏安法 |
Synthesis and Crystal Structure of the Copper Complex of 7,16-Bis(2-hydroxy-5-methylbenzyl)-1,4,10,13- tetraoxa-7,16-diazacyclooctadecane |
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| MA,Shu-Lan ZHU,Wen-Xiang GUO,Qian-Ling LIU,Ying-Chun XU,Miao-Qiong. Synthesis and Crystal Structure of the Copper Complex of 7,16-Bis(2-hydroxy-5-methylbenzyl)-1,4,10,13- tetraoxa-7,16-diazacyclooctadecane[J]. Chinese Journal of Chemistry, 2004, 22(1): 60-63. DOI: 10.1002/cjoc.20040220114 |
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| Authors: | MA Shu-Lan ZHU Wen-Xiang GUO Qian-Ling LIU Ying-Chun XU Miao-Qiong |
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| Affiliation: | MA,Shu-Lan ZHU,Wen-Xiang GUO,Qian-Ling LIU,Ying-Chun XU,Miao-Qiong Department of Chemistry,Beijing Normal University,Beijing 100875,China |
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| Abstract: | A lariat crown ether ligand 7,16-bis (2-hydroxy-5-methylbenzyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane (L1) has been prepared via one-pot Mannich reaction. Its copper(II) complex Cu-L1 was synthesized and charac-terized by elemental analysis, IR and UV-visible spectroscopy. The crystal structure of the complex has been deter-mined by X-ray diffraction analysis. The result shows that the copper(II) ion is six-coordinated by two nitrogen and four oxygen atoms, two from the crown ether and the other two from the deprotonated phenolate anions, forming an elongated octahedral complex. Electrochemical study indicates that the complex undergoes reversible reduction in DMF solution. |
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| Keywords: | N N'-disubstituted diaza-18-crown-6 copper(II) complex crystal structure cyclic voltammetry |
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