Bromine is an endogenous component of a vanadium bromoperoxidase |
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| Authors: | Feiters Martin C Leblanc Catherine Küpper Frithjof C Meyer-Klaucke Wolfram Michel Gurvan Potin Philippe |
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| Institution: | Department of Organic Chemistry, Institute of Molecules and Materials (IMM), Radboud University Nijmegen, 1 Toernooiveld, NL-6525 ED Nijmegen, The Netherlands. |
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| Abstract: | On the basis of EXAFS and MS/MS experimental results and a reinterpretation of the electron density map obtained by X-ray crystallography, we describe a new post-translational modification, that is, a 3,5-dibromotyrosine residue that is incorporated in the polypeptide chain of a vanadium haloperoxidase. |
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