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| N－3－炔丁烯基咔唑的合成及热聚合 | |
| 引用本文： | 王斌,谢守和,叶大铿,张声华.N－3－炔丁烯基咔唑的合成及热聚合[J].有机化学,2003,23(7):650-653. |
| 作者姓名： | 王斌 谢守和 叶大铿 张声华 |
| 作者单位： | 1. 华中农业大学食科系,武汉,430070;军事经济学院军需系,武汉,430035 2. 军事经济学院军需系,武汉,430035 3. 中山大学化学系,广州,510275 4. 华中农业大学食科系,武汉,430070 |
| 摘 要： | 在室温和高速搅拌下,以十六烷基三甲基溴化铵为相转移催化剂,往咔唑和 50％NaOH水溶液中缓慢滴加1,4－二氯－2－丁炔,反应24h后,经重结晶分离得到 无色针状晶体。IR,~1H NMR,MS,VPO等结构分析方法确定无色针状晶体为反式N －3－炔丁烯基咔唑;加热生成的聚合物为聚炔烃,分子量为1.9-10~3,聚合度为 9;通过DTA－TG分析和热聚合速率的测定,探讨了单体热聚合规律,测得热聚合活 化能为118kJ/mol。聚合物电导率小于10~(-12)S·cm~(-1),而与FeCl_3形成电荷 转移络合物则达到8*10~(-4)S·cm~(-1)。 |
| 关 键 词： | 咔唑 P 十六烷基三甲基溴化铵 相转移催化 氢氧化钠 丁炔 P 重结晶 红外分光光度法 质子磁共振谱法 质谱法 电荷转移氯化物 |
| 修稿时间： | 2002年8月6日 |
Synthesis and Thermal Polymerization of N-3-Yne-butenylcarbazole |
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| WANG,Bin XIE,Shou-He YE,Da-Ken ZHANG,Sheng-Hua.Synthesis and Thermal Polymerization of N-3-Yne-butenylcarbazole[J].Chinese Journal of Organic Chemistry,2003,23(7):650-653. | |
| Authors: | WANG Bin XIE Shou-He YE Da-Ken ZHANG Sheng-Hua |
| Institution: | Department of Food Science, Huazhong Agriculture University;Institute of Nutrition, College of Military Economics;Department of Chemistry, Zhongshan University |
| Abstract: | N-3-Yne-butenylcarbazole has been synthesized by stirring a mixture of carbazole, 1,4-dichloro-2-butyne, benzene, 50% NaOH and cetyl trimethyl ammonium bromide in water. The compound was polymerized by heating. The polymerization activated energy was 118 kj/mol. Molecular weight of the polymer polymerized at 120 t! was 1.9 x l(r (n ?a9). The conductance ratio of the polymer was less than 10 ~12 S? cm~' and that of the charge transfer compound of the polymer with FeCl3 was 8 x 10 ~4 S ? cm"1. |
| Keywords: | N-3-yne-butenylcarbazole synthesis thermal polymerization structural analysis conductance ratio |
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