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Self-assembly of bipolar amphiphiles
Affiliation:1. Soft Matter Nanotechnology Group, CIC biomaGUNE, Paseo Miramón 182C, 20009 San Sebastián, Guipúzcoa, Spain;2. Instituto de Investigaciones Fisicoquimicas Teóricas y Aplicadas (INIFTA), (UNLP, CONICET), Sucursal 4, Casilla de Correo 16, 1900 La Plata, Argentina;3. Experimental Physics, Saarland University, 66123 Sarbruecken, Germany;1. BP Institute and Department of Chemistry, University of Cambridge, Madingley Road, Cambridge, Cambs CB3 0EZ, UK;2. ISIS, Rutherford Appleton Laboratory, Didcot, Oxfordshire, UK;1. Institute of Pharmacy, Martin-Luther-University Halle-Wittenberg, Halle (Saale), Germany;2. Institute of Pharmaceutical Science, School of Cancer and Pharmaceutical Science, King’s College London, London, UK;1. Department of Polymer Science, College of Polymer Science and Polymer Engineering, The University of Akron, Akron, OH 44325-3909, USA;2. Department of Chemical Engineering and Frontier Center of Fundamental and Applied Sciences of Matters, National Tsing Hua University, Hsin-Chu 30013, Taiwan;3. Department of Applied Chemistry, National Chiao Tung University, 1001 Ta Hsueh Road, Hsin-Chu 30010, Taiwan;4. Department of Polymer Science and Engineering, College of Chemistry and Molecular Engineering, Center for Soft Matter Science and Engineering, Peking University, Beijing 100871, China;1. Key Laboratory of Colloid and Interface Chemistry (Ministry of Education), Shandong University, Jinan 250100, PR China;2. National Engineering Technology Research Center for Colloidal Materials, Shandong University, Jinan 250100, PR China
Abstract:Over the past 2 years, various symmetrical and unsymmetrical bipolar amphiphiles (bolaamphiphiles) have been synthesized to study their self-organizing and packing properties alone as well as in mixtures with conventional amphiphiles. This review focuses on the lyotropic properties of these bolaamphiphiles and describes their in some cases quite unusual supramolecular self-assembling properties in aqueous media and at the air–water and liquid–solid interface.
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