Self-assembled structures and chemical reactions in room-temperature ionic liquids |
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Affiliation: | 1. Biophysical Chemistry Laboratory, Centre for Interdisciplinary Research in Basic Sciences, Jamia Millia Islamia, New Delhi 110025, India;2. Department of Chemistry, King Abdulaziz University, Jeddah 21589, Saudi Arabia;3. Surface Chemistry and Catalytic Studies group, SCCS, Department of Chemistry, King Abdulaziz University, Jeddah 21589, Saudi Arabia |
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Abstract: | Amphiphilic association in room-temperature ionic liquids (RT-ILs) — a “green” solvent shows analogies as well as clear differences from self-assembly in water. In this review, we summarize the known features of amphiphilic association structures in the form of micelles, microemulsions, vesicles and lyotropic liquid-crystalline phases in ionic liquids. Most of the methods making use of association to control reactivity could be developed also in RT-ILs and we give a few recently published examples of this strategy. |
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