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Sulphur conductive solid electrolytes in MeS–Ln2S3 systems
Institution:1. Chemistry Department, Vyatka State University, Moscvovskaya 36, Kirov 610000, Russia;2. St. Petersburg State University, University pr. 2, Petrodvorez, St. Peterburg 198504, Russia
Abstract:The principal possibility of sulphide transfer in phases based on BaZrS3 and MLn2S4 has been considered. The regions of solid solutions based on tertiary compounds have been defined. The systematic study of these phases by methods of conductometry, EMF in chemical concentration chains with and without transfer, potentiostatic chronoamperometry has been performed. A possible defect forming mechanism at consecutive alloying of the tertiary sulphides by the binary ones has been suggested.
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