The oxidation of fullerene[C60] with various amine N-oxides under ultrasonic irradiation |
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| Authors: | Ko Weon-Bae Nam Je-Heon Hwang Sung-Ho |
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| Affiliation: | Department of Chemistry, Sahmyook University, Seoul 139-742, South Korea. kowb@syu.ac.kr |
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| Abstract: | The reaction of C60 with various amine N-oxides such as 3-picoline N-oxide (Aldrich 98.0%), pyridine N-oxide hydrate (Aldrich 95.0%), quinoline N-oxide (Aldrich 97.0%), isoquinoline N-oxide (Aldrich 98.0%) under ultrasonic irradiation in air at 25-43 degrees C causes the oxidation of fullerene[C60(O)n] (n=1-2 or n=1). The MALDI-TOF MS, UV-vis spectra, and HPLC profile confirmed that the products of fullerene oxidation are [C60(O)n] (n=1-2 or n=1). |
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