Synthesis and Structure of the Supramolecular Adduct Formed by the [Mo3S4(H2O)7Cl22+ Cluster Complex with Cucurbituril: {[Mo3S4(H2O)7Cl2](C36H36N24O12)} Cl2·10H2O |
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| Authors: | E V Chubarova D G Samsonenko J H Platas M N Sokolov and V P Fedin |
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| Institution: | (1) A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia;(2) University of La Laguna, Tenerife, Spain |
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| Abstract: | Slow crystallization of an HCl solution containing cucurbituril (C36H36N24O12) and a triangular molybdenum cluster aqua complex Mo3S4(aq)]4+ yielded a supramolecular adduct of { Mo3S4(H2O)7Cl2]×(C36H36N24O12)Cl2·10H2O composition. The molecular and crystal structure of the adduct were established by single crystal X-ray diffraction. Monoclinic crystal system, space group P21/c, a = 21.4762(2) Å, b = 14.6853(1) Å, c = 24.6480(3) Å; β = 112.8366(5)°, V
cell = 7164.26(12) Å3, Z = 4, ρcalc = 1.725 g/cm3.Original Russian Text Copyright © 2004 by E. V. Chubarova, D. G. Samsonenko, J. H. Platas, M. N. Sokolov, and V. P. Fedin__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 950–954, September–October, 2004. |
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| Keywords: | molybdenum cucurbituril cluster |
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