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Synthesis und Reaktivität von Dimethylaminoalkylidenaminooxy-arsinen |
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| Authors: | J Kaufmann F Kober |
| Abstract: | Synthesis and Reactivity of Dimethylaminoalkylideneaminooxiarsines The reactions of AsN(CH3)2]3 with oximes result in the formation of the oximates (CH3)2N]2AsONCRR′, (CH3)2N As(ONCRR′)2 and As(ONCRR′)3. The eleavage of the As-N-bond with alcohols, thiols and diols are described. The reactions of CH3AsN(CH3)2]ONCRR′ with water, amine and alcohols are examined. IR-and 1H-NMR-spectral data are presented. |
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