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笼形聚偕胺肟树脂吸附贵金属──无机酸处理对树脂吸附性能的影响
引用本文:吴锦远,杨超雄. 笼形聚偕胺肟树脂吸附贵金属──无机酸处理对树脂吸附性能的影响[J]. 广州化学, 1996, 0(2)
作者姓名:吴锦远  杨超雄
作者单位:中国科学院广州化学研究所!广州
摘    要:笼形聚偕胺后树脂分别用硼酸、硝酸、磷酸、硫酸和氢卤酸处理后,对Ag+、AuC、IrC、NdC、和PtC离子的吸附容量都发生显著的差异,吸附能力与处理酸的阴离子在偕胺肟基上的结合程度有关。研究了硼酸处理树脂对上述离子的吸附动力学,讨论了吸附机理。

关 键 词:笼形树脂  聚偕胺肟  贵金属  无机酸  吸附作用

Noble metals adsorbed by cage polyamidoxime adsorbents-effect of the adsorbents treated by inorganic acids on adsorptivity
Wu Jinyuan, Yang Chaoxiong. Noble metals adsorbed by cage polyamidoxime adsorbents-effect of the adsorbents treated by inorganic acids on adsorptivity[J]. Guangzhou Chemistry, 1996, 0(2)
Authors:Wu Jinyuan   Yang Chaoxiong
Abstract:The cage polyamidoxime resins were treated with boric acid, nitric acid, phosphoricacid, sulfuric acid, hydrofluoric acid, hydrochloric acid and hydroiodic acid, respectively.The adsorbents obtained (HX/ACAO) are widely different in adsorption capacity for Ag, AuC, IrC, PdC, and PtC ions. It is considered that the adsorptivity depends upon the extent of the acid anions combine with the amidoxime groups. The adsorption kinetics was investigated and the mechanism was discussed.
Keywords:cage resin   polyamidoxime   noble metal ion   inorganic acid   adsorption
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