Thermal analysis of boron complexes containing ligands of the type R-C(CH2OH)3 |
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Authors: | J M Schwarz A F Ievins A A Terauda A A Vegnere |
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Institution: | 1. Institute of Inorganic Chemistry, Riga, USSR
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Abstract: | The thermal behaviours of certain salts of the complex “ethriol-” and “methriolboric” acids have been investigated by means of Derivatograph and IR spectra. It is shown that compounds of this type decompose in three main stages on heating: 1) the crystallization water is lost, 2) the condensation water is lost and dimers are formed containing bridge bonds B4-O-B4; 3) up to 600–700? all the organic matter is lost; the residue is the corresponding borate (1 ∶ 1). The possibility of performing a fast full analysis by means of the TG and DTG curves has been demonstrated. |
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