Novel Cu(I) dinuclear complexes containing mu2-eta(2),eta(2)-type benzoquinone ligand |
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| Authors: | Masaoka Shigeyuki Akiyama George Horike Satoshi Kitagawa Susumu Ida Tomohiko Endo Kazunaka |
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| Affiliation: | Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 Japan. |
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| Abstract: | Novel Cu(I) complexes containing a mu2-eta2,eta2-type benzoquinone ligand have been synthesized and crystallographycally characterized. These complexes are synthesized by the redox reaction of a copper-quinonoid pair and may indicate a significant intermediate in the Cu-BQ catalytic system. Moreover, this study is regarded as one of the good examples in the Cu(I)-olefin family of enhanced pi-back-donation. |
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