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Chiral Steroidal Phosphines: Synthesis and Platinum Complexes |
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| Authors: | Rita Skoda-F?ldes Laura Bánffy Judit Horváth Zoltán Tuba and László Kollár |
| Abstract: | The synthesis of novel 3- and 17-diphenylphosphino-androstane derivatives via homogeneous catalytic P-C coupling is described. The products were characterized by 1H and 31P NMR measurements. According to the NMR investigation of the PtCl2P2-type complexes, the steroidal phosphines are trans-coordinated with respect to the Pt-centre exclusively. |
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