Synthesis and photoactivated insecticidal activity of tetraethynylsilanes |
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Authors: | Guang Shao Ding-Xin Jiang Han-Hong Xu Wei Zeng Hui-Juan Yu Yong-Qing Tian |
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Institution: | 1. School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, PR China;2. Key Laboratory of Natural Pesticide and Chemical Biology, Ministry of Education, Laboratory of Insect Toxicology, South China Agricultural University, Guangzhou 510642, PR China |
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Abstract: | A series of tetraethynylsilanes (TETS) have been synthesized by reaction of silicon tetrachloride (SiCl4) with Ar–C CLi, which was prepared in situ by treatment of Ar–C CH with n-BuLi. For these TETS thus prepared, their photoactivated insecticidal activities against the 4th-instar larvae of Aedes albopictus (Skuse) were evaluated to enrich the structure–activity relationship. In particular, compound 8 exhibited excellent photoactivated insecticidal activity, the LC50 value was 0.1346 mg L?1 under UV light treatment and the irradiation-generated enhancement in the activity was more than 69.58-fold, thus could be exploitable as ideal analog candidates in the search for new photoactivated insecticide leads. |
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