Preparation of hydrogels by photopolymerization of acrylates in the presence of Type I and one-component Type II photoinitiators |
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Authors: | Nurcan Karaca Gokhan Temel Demet Karaca Balta Meral Aydin Nergis Arsu |
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Institution: | Yildiz Technical University, Department of Chemistry, Davutpasa Campus, Istanbul 34210, Turkey |
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Abstract: | Hydrogels were prepared by photoinduced polymerization of poly(ethylene glycol)monoacrylate (PEGMA) and poly(ethylene glycol)diacrylate (n = 200 and 700) (PEGDA) with Type I, 1-4-(2-hydroxyethoxy)-phenyl]-2-hydroxy-2-methyl-1-propane-1-one (I-2959) and one-component Type II initiators: (9-oxo-9H-thioxanthen-2-yloxy)-acetic acid (TXOCH2COOH) and (9-oxo-9H-thioxanthen-2-yloxy)-sodium acetate (TXOCH2COO?Na+). The swelling properties of hydrogels were investigated and observed to be excellent. Smooth morphology and no phase separation were observed from SEM micrographs of the hydrogels. |
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