[Zn(NH3)4][PtCl6] and [Cd(NH3)4][PtCl6] as precursors for intermetallic compounds PtZn and PtCd |
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| Authors: | A. V. Zadesenets A. B. Venediktov Yu. V. Shubin S. V. Korenev |
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| Affiliation: | (1) Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia |
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| Abstract: | Double complex salts (tetraamminezinc and tetraamminecadmium hexachloroplatinates) have been synthesized. Their thermal properties have been studied, as well as the products of their degradation in hydrogen and helium atmospheres. Optimal thermolysis schedules have been determined. Thermolysis under hydrogen yields intermetallic compounds PtZn and PtCd. |
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