Formation of disilanes in the reaction of stable silylenes with halocarbons |
| |
Authors: | Moser Daniel F Naka Akinobu Guzei Ilia A Müller Thomas West Robert |
| |
Affiliation: | Organosilicon Research Center, Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53607, USA. |
| |
Abstract: | Reactions of stable silylenes 1 and 2 with a variety of halogenated organic compounds have been studied. Depending on the nature of the halocarbon, the products can be disilanes, LSiX-LSiR, or monosilanes, LSiXR, or a mixture of both types of products. Hexachloroethane reacts with the silylenes to give mainly the dichlorodisilane, LSiX-LSiX. The experimental results are rationalized in terms of several related free-radical chain mechanisms. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|